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                                Nwosu-Obieogu, K.
                             
                                Chemical Engineering Department, Michael Okpara University of Agriculture, Umudike, Abia state
                             
 
                                Aguele, F. O.
                             
                                Chemical Engineering Department, Michael Okpara University of Agriculture, Umudike, Abia state
                             
 
                                Chiemenem, L. I.
                             
                                Chemical Engineering Department, Michael Okpara University of Agriculture, Umudike, Abia state
                             
 
 ABSTRACT
 
 
 
                        
Currently, interest in cheap and
biodegradable polymeric materials has encouraged its development from readily
available, renewable, inexpensive natural sources such as polysaccharides and
vegetable oils. Although a major setback to using a bio-based polymer from
plant oils is the high viscosity, which makes impregnation of fibers difficult.
This work proffers a solution by synthesizing a thermoset resin from linseed
and sunflower oils through epoxidation by reactions with formic acid (HCOOH)
and hydrogen peroxide (H202) at a temperature of 60oC
and the further modification was done using acetic acid, in the presence of
hydroquinone as a free radical inhibitor) at a temperature of 120oC.
The epoxidised and modified oil resins were obtained and characterized using
FT-IR spectroscopy. From the analysis, the oils were suitably functionalised and
its viscosity reduced. 
 Keywords: epoxidation, modification, linseed oil, sunflower oil, viscosity
 
 
 
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                        Published
                     
                        Sunday, December 31, 2017
                     
 
                        Issue
                     
                        Vol. 3 No. 2, DEC 2017
                     
 
                        Article Section
                     
                        GENERAL
                     
 
                        
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