Umudike Journal of Engineering and Technology

Michael Okpara University of Agriculture, Umudike


PRODUCTION OF BIOBASED POLYMERIC RESINS FROM MODIFIED LINSEED OIL AND SUNFLOWER OIL

Nwosu-Obieogu, K.
Chemical Engineering Department, Michael Okpara University of Agriculture, Umudike, Abia state

Aguele, F. O.
Chemical Engineering Department, Michael Okpara University of Agriculture, Umudike, Abia state

Chiemenem, L. I.
Chemical Engineering Department, Michael Okpara University of Agriculture, Umudike, Abia state



ABSTRACT

Currently, interest in cheap and biodegradable polymeric materials has encouraged its development from readily available, renewable, inexpensive natural sources such as polysaccharides and vegetable oils. Although a major setback to using a bio-based polymer from plant oils is the high viscosity, which makes impregnation of fibers difficult. This work proffers a solution by synthesizing a thermoset resin from linseed and sunflower oils through epoxidation by reactions with formic acid (HCOOH) and hydrogen peroxide (H202) at a temperature of 60oC and the further modification was done using acetic acid, in the presence of hydroquinone as a free radical inhibitor) at a temperature of 120oC. The epoxidised and modified oil resins were obtained and characterized using FT-IR spectroscopy. From the analysis, the oils were suitably functionalised and its viscosity reduced.



Keywords: epoxidation, modification, linseed oil, sunflower oil, viscosity


View: 242 | Download: 8

Published
Sunday, December 31, 2017

Issue
Vol. 3 No. 2, DEC 2017

Article Section
GENERAL

The contents of the articles are the sole opinion of the author(s) and not of UJET.


Open Access
Umudike Journal of Engineering and Technology makes abstracts and full texts of all articles published freely available to everyone immediately after publication thereby enabling the accessibility of research articles by the global community without hindrance through the internet.

Indexing and Abstracting
We are index in Google Scholar, AJOL, and EBSCO.